Thermoelectric properties of nanoporous Ge
نویسندگان
چکیده
We computed thermoelectric properties of nanoporous Ge !np-Ge" with aligned pores along the #001$ direction through a combined classical molecular dynamics and first-principles electronic structure approach. A significant reduction in the lattice thermal conductivity of np-Ge leads to a 30-fold increase in the thermoelectric figure-of-merit !ZT" compared to that of bulk. Detailed comparisons with the recently proposed np-Si show that although the maximum ZT !ZTmax" of Ge is nine times larger than that of Si in the bulk phase, ZTmax of np-Ge is twice as large as that of np-Si due to the similarity in lattice thermal conductivity of the two np systems. Moreover, ZTmax is found to occur at a carrier concentration two orders of magnitude lower than that for with np-Si due to the dissimilarities in their electronic structure. © 2009 American Institute of Physics. #DOI: 10.1063/1.3159813$
منابع مشابه
Structure and Thermoelectric Properties of Bi2−xSbxTe3 Nanowires Grown in Flexible Nanoporous Polycarbonate Templates
متن کامل
Structure and Thermoelectric Properties of Bi2-xSbxTe₃ Nanowires Grown in Flexible Nanoporous Polycarbonate Templates.
We report the room-temperature growth of vertically aligned ternary Bi2-xSbxTe₃ nanowires of diameter ~200 nm and length ~12 µm, within flexible track-etched nanoporous polycarbonate (PC) templates via a one-step electrodeposition process. Bi2-xSbxTe₃ nanowires with compositions spanning the entire range from pure Bi₂Te₃ (x = 0) to pure Sb₂Te₃ (x = 2) were systematically grown within the nanopo...
متن کاملEXPERIMENTAL EVIDENCE OF IMPROVED THERMOELECTRIC PROPERTIES AT 300K IN Si/Ge SUPERLATTICE STRUCTURES
We have found that it may be possible to obtain significant enhancement in ZT at 300K, over conventional bulk SiGe alloys, through the use of Si/Ge Superlattice (SL) structures. The Seebeck coefficient in Si/Ge SL structures was observed to increase rapidly with decreasing SL period with no loss of electrical conductivity. The carrier mobilities in Si/Ge SLs were higher than in a comparable thi...
متن کاملGiant Seebeck effect in Ge-doped SnSe
Thermoelectric materials may contribute in the near future as new alternative sources of sustainable energy. Unprecedented thermoelectric properties in p-type SnSe single crystals have been recently reported, accompanied by extremely low thermal conductivity in polycrystalline samples. In order to enhance thermoelectric efficiency through proper tuning of this material we report a full structur...
متن کاملNanoporous Si as an efficient thermoelectric material.
Room-temperature thermoelectric properties of n-type crystalline Si with periodically arranged nanometer-sized pores are computed using a combination of classical molecular dynamics for lattice thermal conductivity and ab initio density functional theory for electrical conductivity, Seebeck coefficient, and electronic contribution to the thermal conductivity. The electrical conductivity is foun...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره شماره
صفحات -
تاریخ انتشار 2009